Вестник Нижегородского университета им. Н.И. Лобачевского. Серия: Социальные науки

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Title of Article

Quantum-chemical and spectrometric study of complex formation in reactions of hetarene sulfenyl chlorides with lithium perchlorate

Issue	6
Date	2008

Article type	scientific article	UDC	547.592+548.75
Pages	83-87	Keywords

Authors

Osmanov V.K.Nizhegorodskiy gosudarstvennyy tekhnicheskiy universitet im. R.E. Alekseeva
Matsulevich Zh.V.Nizhegorodskiy gosudarstvennyy tekhnicheskiy universitet im. R.E. Alekseeva
Borisova G.N.Nizhegorodskiy gosudarstvennyy tekhnicheskiy universitet im. R.E. Alekseeva
Zelentsov S.V.Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo
Borisov A.V.Nizhegorodskiy gosudarstvennyy tekhnicheskiy universitet im. R.E. Alekseeva

Abstract

The existence of electrophilic complexes with bidentate coordination of lithium cation to chlorine and nitrogen atoms of sulfenyl chloride molecule in hetarene sulfenyl chloride – lithium perchlorate systems has been proved by quantum-chemical calculations (B3LYP /6–31G(d) level) and spectral (IR and 1H NMR) methods.

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