The statistical Monte-Carlo method is used to simulate the process of three-dimensional polymerization of diallyl isophthalate (DAIP). During the process of three-dimensional free-radical polymerization of allyl compounds, the chain transfer to monomer reaction is observed which yields molar-mass distribution rather than a uniform polymer skeleton. The influence of the mechanism of chain transfer to the monomer on kinetic characteristics of DAIP polymerization is considered taking into account the simulation of diffusion control conditions.
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