Вестник Нижегородского университета им. Н.И. Лобачевского. Серия: Социальные науки

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Title of Article

ANILINE OXIDATIVE POLYMERIZATION AS A PROCESS OF HETEROGENEOUS CATALYSIS

Issue	6
Date	2012

Section

CHEMISTRY

Article type		UDC	547. 551. 1: (678.5 + 541. 12)
Pages	69-75	Keywords

Authors

Mezhuev Yaroslav OlegovichRossiyskiy khimiko-tekhnologicheskiy universitet im. D.I. Mendeleeva, Moskva
Korshak Yuriy VasilevichRossiyskiy khimiko-tekhnologicheskiy universitet im. D.I. Mendeleeva, Moskva
Shtilman Mikhail IsaakovichRossiyskiy khimiko-tekhnologicheskiy universitet im. D.I. Mendeleeva, Moskva
Osadchenko Sergey VladimirovichRossiyskiy khimiko-tekhnologicheskiy universitet im. D.I. Mendeleeva, Moskva
Strakhov Igor SergeevichRossiyskiy khimiko-tekhnologicheskiy universitet im. D.I. Mendeleeva, Moskva

Abstract

The kinetics of aniline oxidative polymerization has been studied by the potentiometric technique. This is the first time that a kinetic model of oxidative polymerization has been constructed as a heterogeneous autocatalytical process. The change in the degree of rate of aniline oxidative polymerization has been determined and explained by the monomer concentration and poly-(N-vinylpyrrolidone) being present in the reaction system.

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