CRYSTAL CHEMICAL SYSTEMATICS OF COMPOUNDS MIВVWO6 (MI - H3O, Li, Na, K, Rb, Cs, Tl; ВV - V, Nb, Sb, Ta) |
| 3 | |
| 2011 |
| scientific article | 546.786 | ||
| 102-105 | complex tungsten oxides, crystal-chemical systematics, X-ray radiography, Rietveld method, morphotropic series |
| The analysis has been carried out of structural types in the morphotropic series of compounds of the general
formula MIВVWO6?nH2O (MI -H3O, Li, Na, K, Rb, Cs, Tl; ВV -V, Nb, Sb, Ta; n=0,1). It is shown that the compounds
can crystallize in five different structural types. Crystal-chemical borders of existence have been found for
each structural type. |
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