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Title of Article

EFFECT OF 2,2,3,3-TETRAFLUOROPYL-2-FLUOROACRYLATE ON THE CHARACTERISTICS OF POLYMER FILMS WITH ELECTRICALLY CONTROLLED TRANSPARENCY


Issue
3
Date
2011

Article type
scientific article
UDC
544.23
Pages
116-119
Keywords
polymer dispersed liquid crystal composite, liquid crystal, photopolymerization, 2, 2, 3, 3- tetrafluoropropyl-2-fluoroacrylate, electro-optical properties


Authors
Dzhons Mikhail Mikhaylovich
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Bulgakova Svetlana Aleksandrovna
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo


Abstract
The effect of 2,2,3,3-tetrafluoropropyl-2-fluoro-acrylate as a comonomer in the photopolymerizable system 2- ethylhexyl acrylate-acrylic acid on the electro-optical characteristics of the polymer composite films with liquid crystal E7 has been studied. It is shown that the introduction of fluorinated acrylate results in a more complete phase separation of polymer and liquid crystal phases, and reduces the interfacial adhesion energy. With the optimum content of fluorinated acrylate of about 1-3 mol %, a reduction of driving voltages and memory effect of the films, as well as an increase of contrast is observed.

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