On the role of molecular water and interface atoms МK in structure formation of crystals МK(PUO6)K?nH2O |
| 6 | |
| 2008 |
| CHEMISTRY |
| scientific article | 546.791.6 | ||
| 77-82 |
| A number of uranophosphates of alkaline (Li+, Na+, K+, Rb+, Cs +), alkaline-earth (Mg2+, Ca2+, Sr2+, Ba2+) and
rare-earth (Y3+, La3+, Ln3+) elements have been obtained by the ion exchange method in the system of Mk -
HPUO6?4H2O and direct deposition from the solution. A decisive role of water and the type of interface atom Mk in
the formation of the compound structure has been proved using the data of chemical analysis, X-ray photography,
infrared spectroscopy, and thermography. |
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