PECULIARITIES OF CONTROLLED RADICAL POLYMERIZATION OF (METH)ACRYLATES BY REVERSIBLE ADDITION FRAGMENTATION CHAIN TRANSFER |
5 | |
2009 |
CHEMISTRY |
scientific article | 541.64 | ||
86-89 | controlled radical polymerization, reversible addition-fragmentation chain transfer polymerization, (meth)acrylates |
The controlled reversible addition-fragmentation chain transfer (RAFT) polymerization of ethoxyethylmethacrylate, isobornylmethacrylate, tert-butyl methacrylate and tert-butoxycarbonyloxystyrene has been studied. Is has been shown that only at tert-butoxycarbonyloxystyrene polymerization in the presence of benzyl dithiobenzoate a noticeable narrowing of the chain-length distribution ( |
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