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Title of Article

TELLURIUM AND TUNGSTEN CHLORIDE OXIDATION IN THE HIGH FREQUENCY CAPACITIVE DISCHARGE AND ITS ANALYSIS ON THE BASIS OF CHEMICAL NONEQUILIBRIUM PLASMA MODEL


Issue
1
Date
2010

Section
CHEMISTRY

Article type
scientific article
UDC
537.525:542.943:546.24/.78
Pages
99-107
Keywords
tellurite glasses, plasma-chemical oxidation, tellurium and tungsten chlorides, chemical nonequilibrium plasma model, chemical condensation from low-temperature plasma


Authors
Kutin A.M.
Institut khimii vysokochistykh veschestv RAN, N. Novgorod

Polyakov V.S.
Institut khimii vysokochistykh veschestv RAN, N. Novgorod

Lobanov A.S.
Institut khimii vysokochistykh veschestv RAN, N. Novgorod

Churbanov M.F.
Institut khimii vysokochistykh veschestv RAN, N. Novgorod


Abstract
Tellurite glass samples have been obtained as a result of joint plasma-chemical oxidation of tellurium and tungsten chlorides in a stream of argon and oxygen under HF capacitive discharge. Regimes of calcination and subsequent vitrification of amorphous plasma chemical precipitation have been found by thermogravimetric analysis. The composition of gas and condensed phases has been specified in compliance with experimental data on the basis of the chemical nonequilibrium plasma model. A procedure has also been worked out to calculate supersaturation for further macrokinetic analysis of chemical condensation from low-temperature plasma.

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