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Title of Article

CALORIMETRIC STUDY OF FIFTH-GENERATION POLYSILOXANECARBOSILANE DENDRIMER


Issue
2
Date
 2010

Article type
 scientific article
UDC
544.31.031
Pages
101-108
Keywords
heat capacity, thermodynamic functions, dendrimer, generation, glass transition


Authors
Smirnova N.N.
NII khimii Nizhegorodskogo gosuniversiteta im. N.I. Lobachevskogo

Samosudova Ya.S.
NII khimii Nizhegorodskogo gosuniversiteta im. N.I. Lobachevskogo

Markin A.V.
NII khimii Nizhegorodskogo gosuniversiteta im. N.I. Lobachevskogo

Muzafarov A.M.
Institut sinteticheskikh polimernykh materialov im. N.S. Enikolopova RAN


Abstract
The heat capacity of fifth-generation polysiloxanecarbosilane dendrimer has been determined over the range from 6 to 550 K by the methods of precision adiabatic and dynamic calorimetry. Physical transformations have been revealed and their thermodynamic characteristics have been estimated in the indicated temperature range. The standard thermodynamic functions: the heat capacity ( ) o

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