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Title of Article

SYNTHESIS AND STRUCTURE OF TRIPHENYLANTIMONY DIACRYLATE


Issue
3
Date
2010

Section
CHEMISTRY

Article type
scientific article
UDC
547.113
Pages
95-99
Keywords
triphenylantimony diacrylate, synthesis, X-ray diffraction analysis, molecular structure


Authors
Guschin Aleksey Vladimirovich
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Prytkova Lyudmila Konstantinovna
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Shashkin Dmitriy Vladimirovich
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Dodonov Viktor Alekseevich
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Fukin Georgiy Konstantinovich
Institut metalloorganicheskoy khimii im. G.A. Razuvaeva RAN, Nizhniy Novgorod

Baranov Evgeniy Vladimirovich
Institut metalloorganicheskoy khimii im. G.A. Razuvaeva RAN, Nizhniy Novgorod

Shavyrin Andrey Sergeevich
Institut metalloorganicheskoy khimii im. G.A. Razuvaeva RAN, Nizhniy Novgorod

Rykalin Vladimir Ivanovich
Gosudarstvennyy nauchnyy tsentr ?Institut fiziki vysokikh energiy?, Protvino, Moskovskaya obl


Abstract
Triphenylantimony diacrylate Ph3Sb(O2CCH=CH2)2 has been obtained by the reaction of triphenylantimony with acrylic acid in the presence of tert-butyl hydroperoxide in ether that has been confirmed by the data of the elemental analysis, molecular weight, IR and 1Н NMR spectroscopy. According to X-ray diffraction analysis data, triphenylantimony diacrylate is a trigonal-bipyramidal complex of antimony with three phenyl groups at the base and two acrylic groups at the tops of the bipyramid.

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