TIN-CONTAINING COMPLEXES OF TUNGSTEN AND CHROMIUM IN POLYMERIZATION OF METHYL METHACRYLATE AND STYRENE |
5 | |
2010 |
CHEMISTRY |
scientific article | 547.1 ' 178: [678.744.335+678.746.222] | ||
85-90 | initiating system, tin-containing complexes of tungsten and chromium, polymerization of methyl methacrylate and styrene |
Features of methyl methacrylate and styrene polymerization in the presence of the initiating systems based
on carbon tetrachloride and tetrahydrofuranates of pentacarbonyl tungsten-tin dichloride and pentacarbonyl chromium-
tin dichloride at 80° C have been analyzed. The influence of the metal complexes on molecular-weight characteristics
of synthesized polymers as well as on the rate of polymerization and conversion has been studied. |
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