Вестник Нижегородского университета им. Н.И. Лобачевского. Серия: Социальные науки

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Title of Article

SYNTHESIS AND STRUCTURE OF TETRAPHENYLANTIMONY ACRYLATE AND ITS INSERTION INTO POLYMETHYLMETHACRYLATE

Issue	6
Date	2010

Section

CHEMISTRY

Article type	scientific article	UDC	547.113
Pages	68-72	Keywords	tetraphenylantimony acrylate, synthesis, X-ray structural analysis, molecular structure, copolymerization

Authors

Guschin Aleksey VladimirovichNizhegorodskiy gosuniversitet im. N.I. Lobachevskogo
Shashkin Dmitriy VladimirovichNizhegorodskiy gosuniversitet im. N.I. Lobachevskogo
Scherbakova Tatyana SergeevnaNizhegorodskiy gosuniversitet im. N.I. Lobachevskogo
Somov Nikolay ViktorovichNizhegorodskiy gosuniversitet im. N.I. Lobachevskogo
Baranov Evgeniy VladimirovichInstitut metalloorganicheskoy khimii im. G.A. Razuvaeva RAN
Fukin Georgiy KonstantinovichInstitut metalloorganicheskoy khimii im. G.A. Razuvaeva RAN
Shavyrin Andrey SergeevichInstitut metalloorganicheskoy khimii im. G.A. Razuvaeva RAN
Rykalin Vladimir IvanovichInstitut fiziki vysokikh energiy, Protvino
Dodonov Viktor AlekseevichNizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Abstract

Tetraphenylantimony acrylate Ph4SbO2CCH=CH2 has been obtained by the reaction of pentaphenylantimony with acrylic acid in toluene solution at room temperature, which has been confirmed by the data of elementary analysis, molecular weight, IR and 1Н NMR spectroscopy. According to X-ray structural analysis data, the substance is a trigonal-bipyramidal complex of the antimony atom with three phenyl groups at the base and acrylic and phenyl ligands at the apices of the bipyramid. Transparent and soluble in chloroform polymer blocks have been obtained by copolymerization of tetraphenylantimony acrylate and MMA.

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