SYNTHESIS, SPECTROSCOPIC STUDY AND FACTOR GROUP ANALYSIS OF CHLORIDE TRISVANADATES OF DIVALENT CATIONS (VO4)3Cl (MII = Ca, Sr, Ba, Cd, Pb) |
| 3 | |
| 2012 |
| scientific article | 543.422.3-74 : 543.424.2 | ||
| 87-91 | apatite, solid-phase synthesis, IR spectroscopy, Raman spectroscopy |
| Apatite-structure compounds with the general formula (VO4)3Cl (MII = Ca, Sr, Ba, Cd, Pb) have been synthesized by a solid-phase reaction. The compounds have been studied using IR, far-IR, and Raman spectroscopic techniques. Factor group analysis has been performed and band assignment has been made in the absorption spectra. Luminescence of Ba5(VO4)3Cl has been observed for the first time. |
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