SYNTHESIS OF POLYACRYLONITRILE IN THE PRESENCE OF CYCLOPENTADIENYLDICARBONYLIRON DIMER |
| 3 | |
| 2012 |
| scientific article | 541.64:546.725:547.339.2 | ||
| 99-104 | cyclopentadienyldicarbonyliron dimer, polymerization, polyacrylonitrile, molecular weight characteristics |
| The composition of cyclopentadienyldicarbonyliron dimer [CpFe(CO)2]2 and carbon tetrachloride has been shown to be an active initiator of radical polymerization of acrylonitrile which allows modifying molecular weight characteristics of synthesized polyacrylonitrile. The choice of solvent and its concentration have been found to play a decisive role in the formation of polymers with a certain molecular weight. |
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