STUDY OF SOLVENT INFLUENCE ON COMPLEXING PROCESSES OF CYCLOPENTADIENE COMPLEXES WITH Zr AND Hf BY THE TRIPLET-TRIPLET ENERGY TRANSFER METHOD |
4 | |
2013 |
scientific article | 544.522.12; 544.522.123; 544.142.3 | ||
118-122 | triplet-triplet energy transfer, ligand-to-metal charge transfer, phosphorescence, exchange resonance energy transfer, organometallic ?-complexes of zirconium and hafnium, cyclopentadiene. |
The article studies the solvent influence on the complexing processes of organometallic ?-complexes of zirconium and hafnium and cyclopentadiene in glassy organic solvents at 77 K by the triplet-triplet energy transfer method. It is found that the sphere radius of a non-radiative energy transfer depends on the solvatation of the organometallic complexes studied. |
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