SYNTHESIS OF GRAFT COPOLYMERS OF POLYVINYL CHLORIDE-POLYSTYRENE UNDER RADICAL INITIATION CONDITIONS |
4 | |
2014 |
scientific article | 678.743.22-13 | ||
147-153 | radical polymerization, nitroxide radicals, polyvinyl chloride (PVC), polystyrene (PS), graft copolymer, reversible inhibition |
A method of synthesis of graft copolymers is proposed based on PVC-PS under radical initiation conditions using 2-methyl-2,3-diphenyl-1,4-diazaspiro[4,5]deca-3-ene-1-oxyl as a polymerization regulator by the reversible inhibition mechanism. The glass transition temperature of the synthesized polymers has been determined by differential scanning calorimetry. |
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