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Title of Article

SYNTHESIS OF GRAFT COPOLYMERS OF POLYVINYL CHLORIDE-POLYSTYRENE UNDER RADICAL INITIATION CONDITIONS


Issue
4
Date
2014

Article type
scientific article
UDC
678.743.22-13
Pages
147-153
Keywords
radical polymerization, nitroxide radicals, polyvinyl chloride (PVC), polystyrene (PS), graft copolymer, reversible inhibition


Authors
Pavlovskaya M.V.
NII khimiiNizhegorodskogo gosuniversiteta im. N.I. Lobachevskogo

Markin A.V.
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo

Smirnova N.N.
NII khimiiNizhegorodskogo gosuniversiteta im. N.I. Lobachevskogo

Grishin D.F.
Nizhegorodskiy gosuniversitet im. N.I. Lobachevskogo


Abstract
A method of synthesis of graft copolymers is proposed based on PVC-PS under radical initiation conditions using 2-methyl-2,3-diphenyl-1,4-diazaspiro[4,5]deca-3-ene-1-oxyl as a polymerization regulator by the reversible inhibition mechanism. The glass transition temperature of the synthesized polymers has been determined by differential scanning calorimetry.

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